Hot Toddy Heat Protectant Mist
May 17 2024 4:41pm SAFETY DATA SHEET
Issue Date 29-Jan-2018 Revision Date 10/8/22 Version 2
1. IDENTIFICATION
Product identifier
Product Name Hot Toddy Heat Protectant Mist - All Variants
Other means of identification
Product Code 19-0780
UN/ID no. UN 1950 IMCO Class 2.1 None Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use Hair Styling Product
Uses advised against No information available
Details of the supplier of the safety data sheet
Supplier Identification Address Telephone Emergency telephone number | Drybar Products LLC/Helen of Troy 1 Helen of Troy Plaza El Paso,Texas, 79912 Phone: 1-800-487-7273 prousso@helenoftroy.com VelocityEHS (Chemtel) 1-800-255-3924 |
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Carcinogenicity | Category 1A |
Flammable aerosols
| Category 1
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Gases under pressure
| Compressed gas
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Label elements
Emergency Overview
Danger
Hazard statements
May cause cancer
Extremely flammable aerosol
Contains gas under pressure; may explode if heated
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Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Pressurized container: Do not pierce or burn, even after use
Do not spray on an open flame or other ignition source
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
Precautionary Statements - Storage
Store locked up
Protect from sunlight. Store in a well-ventilated place
Do not expose to temperatures exceeding 122 °F (50 °C)
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) Not applicable
Other Information
Toxic to aquatic life with long lasting effects Harmful to aquatic life
Unknown acute toxicity 99.262% of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Synonyms None.
Chemical Name | CAS No. | Weight-% |
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Ethanol | 64-17-5 | 15 - 40 |
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Aminomethyl propanol | 124-68-5 | 0.1 - 1 |
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4. FIRST AID MEASURES
Description of first aid measures |
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Eye contact | Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. | |
Skin contact | Discontinue use of product. Wash affected area with soap and water. If discomfort persists, consult a physician. | |
Inhalation | If respiratory irritation occurs, remove individual to fresh air. If discomfort persists, consult a physician. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. If breathing is affected due to intentional inhalation, remove patient to fresh air, get emergency attention, and administer artificial respiration and/or oxygen. |
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Ingestion | Clean mouth with water and drink afterwards plenty of water. |
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Most important symptoms and effects, both acute and delayed
Symptoms No information available.
Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). CAUTION: Use of water spray when fighting fire may be inefficient.
Specific hazards arising from the chemical No information available.
Hazardous combustion products Hydrocarbons, Volatile organic compounds, Halocarbons, Dimethyl Ether
Explosion data
Sensitivity to Mechanical Impact No information available.
Sensitivity to Static Discharge May be ignited by heat, sparks or flames.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions | Ensure adequate ventilation, especially in confined areas. |
For emergency responders Environmental precautions | Be aware that gases can spread at ground level (heavier than air) and pay attention to the wind direction. Remove all sources of ignition. Pay attention to flashback. Wear respiratory protection. Ventilate the area. |
Environmental precautions | The product ingredients are expected to be safe for the environment at concentrations predicted under normal use and accidental spill scenarios. Packaging components are compatible with conventional solid waste management practices. Aerosol containers are recyclable when empty. |
Methods and material for containment and cleaning up
Methods for containment | Prevent further leakage or spillage if safe to do so. |
Methods for cleaning up | Dispose of in accordance with federal, state and local regulations. |
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Flammable. Avoid heat, sparks, flame, or smoking during use. Use only in well-ventilated areas. Contents under pressure. Do not crush, puncture or incinerate. Keep out of reach of children.
Conditions for safe storage, including any incompatibilities
Storage Conditions | Store as an aerosol under the proper aerosol classification level in accordance with NFPA 30B. Store in a cool, dry, well-ventilated area below 120°F. Warehousing should be in compliance with local, state, and federal codes, as well as the regulations of your insurance carrier. |
Packaging materials | No information available. |
Incompatible materials | None known based on information supplied. |
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Chemical Name | ACGIH TLV | OSHA PEL | NIOSH IDLH |
Ethanol 64-17-5 | STEL: 1000 ppm | TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 | IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 |
Appropriate engineering controls
Engineering Controls Showers
Eyewash stations
Ventilation systems.
Individual protection measures, such as personal protective equipment
Eye/face protection Avoid contact with eyes.
Skin and body protection No special technical protective measures are necessary.
Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state | Aerosol |
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Appearance | Spray | Odor | No information available |
Color
| No information available | Odor threshold
| No information available |
Property
| Values | Remarks • Method
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pH
| No information available |
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Melting point / freezing point
| No information available |
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Boiling point / boiling range | No information available |
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Boiling point concentrate | 78.5 °C |
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Boiling point propellant | 25.1 °C |
Flash point
| No information available |
Flash point concentrate | 13 °C 55.4 °F |
Flash point propellant | -50 °C |
Evaporation rate | No information available |
Flammability (solid, gas)
Flammability Limit in Air | No information available |
Upper flammability limit: | No information available |
Lower flammability limit: | No information available |
Vapor pressure | No information available |
Vapor density
| No information available |
Relative density | No information available |
Water solubility | No information available |
Solubility in other solvents | No information available |
Partition coefficient
| No information available |
Autoignition temperature | No information available |
Decomposition temperature
| No information available |
Kinematic viscosity | No information available |
Dynamic viscosity
| No information available |
Explosive properties | No information available |
Oxidizing properties Other Information | No information available |
Softening point | No information available |
Molecular weight | No information available |
VOC Content (%) | <55% |
Density | 0.7908 g/cc |
Bulk density | No information available |
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions None under normal processing.
Conditions to avoid
Extremes of temperature and direct sunlight.
Incompatible materials
None known based on information supplied.
Hazardous Decomposition Products
None known based on information supplied.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information | No data available |
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Inhalation | No data available. |
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Eye contact | No data available. |
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| Skin contact | No data available. |
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| Ingestion | No data available. |
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| Chemical Name | Oral LD50 | Dermal LD50 | Inhalation LC50 | ||
| Ethanol 64-17-5 | = 7060 mg/kg ( Rat ) | - | = 124.7 mg/L ( Rat ) 4 h | ||
| Aminomethyl propanol 124-68-5 | = 2900 mg/kg ( Rat ) | > 2000 mg/kg ( Rabbit ) | - | ||
Information on toxicological effects
Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available.
Chemical Name |
| ACGIH | IARC | NTP | OSHA |
Ethanol 64-17-5 |
| A3 | Group 1 | Known | X |
Reproductive toxicity | No information available. |
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STOT - single exposure | No information available. |
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STOT - repeated exposure | No information available. |
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Aspiration hazard | No information available. |
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Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 6,317.00 ATEmix (dermal) 12,725.00 ATEmix (inhalation-dust/mist) 127.10 |
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12. ECOLOGICAL INFORMATION |
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Ecotoxicity
43.918 % of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name | Algae/aquatic plants | Fish | Crustacea |
Ethanol 64-17-5 | - | 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static | 9268 - 14221: 48 h Daphnia magna mg/L LC50 10800: 24 h Daphnia magna mg/L EC50 2: 48 h Daphnia magna mg/L EC50 Static |
Disiloxane 107-46-0 | - | 3.02: 96 h Oncorhynchus mykiss mg/L LC50 flow-through | 314: 24 h Daphnia magna mg/L EC50 |
Aminomethyl propanol 124-68-5 | 520: 72 h Desmodesmus subspicatus mg/L EC50 | 190: 96 h Lepomis macrochirus mg/L LC50 static | 193: 48 h Daphnia magna mg/L EC50 |
Glycerin 56-81-5 | - | 51 - 57: 96 h Oncorhynchus mykiss mL/L LC50 static | 500: 24 h Daphnia magna mg/L EC50 |
Persistence and degradability No information available.
Bioaccumulation
No information available.
| Chemical Name | Partition coefficient | ||
| Ethanol 64-17-5 | -0.32 | ||
Other adverse effects | No information available |
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13. DISPOSAL CONSIDERATIONS
Waste treatment methods |
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Disposal of wastes | Disposal should be in accordance with applicable regional, national and local laws and regulations. |
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Contaminated packaging | Do not reuse container. |
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| Chemical Name | California Hazardous Waste Status | ||||
| Ethanol 64-17-5 |
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| Toxic Ignitable | ||
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| 14. TRANSPORT INFORMATION |
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| DOT | Regulated |
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| UN/ID no. | UN 1950 IMCO Class 2.1 |
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| Proper shipping name | Aerosols, Flammable - Limited Quantity |
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| Hazard Class | 2.1 |
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| Packing Group | n/a |
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| IATA | Regulated |
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| UN/ID no. | UN 1950 IMCO Class 2.1 |
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| Proper shipping name | Aerosols, Flammable - Limited Quantity |
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| Hazard Class | 2.1 |
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| Packing Group | n/a |
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| IMDG | Regulated |
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| UN/ID no. | UN 1950 IMCO Class 2.1 |
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| Proper shipping name | Aerosols, Flammable - Limited Quantity |
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| Hazard Class | 21 |
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| Packing Group | n/a |
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| EmS-No. | Chemtrec 1-800-424-9300 |
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| 15. REGULATORY INFORMATION |
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International Inventories
TSCA Does not comply
DSL/NDSL Does not comply
EINECS/ELINCS Does not comply
ENCS Does not comply
IECSC Does not comply
KECL Does not comply
PICCS Does not comply
AICS Does not comply
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories |
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Acute health hazard | No |
Chronic Health Hazard | No |
Fire hazard | No |
Sudden release of pressure hazard | No |
Reactive Hazard | No |
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
U.S. EPA Label Information
EPA Pesticide Registration Number Not applicable
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA
| Health hazards 0 Flammability 0 | Instability 0 | Physical and Chemical |
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| Properties -
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HMIS
| Health hazards 0 Flammability 0 | Physical hazards 0 | Personal protection X |
Issue Date | 29-Jan-2018 |
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Revision Date | 10/8/22 |
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Revision Note | Emergency company data updated. DR |
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No information available Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet