Hot Toddy Heat Protectant Mist

May 17 2024 4:41pm

                                 SAFETY DATA SHEET 

Issue Date          29-Jan-2018                                      Revision Date  10/8/22                                                                                      Version   2

1. IDENTIFICATION

Product identifier 

Product Name                                            Hot Toddy Heat Protectant Mist - All Variants

Other means of identification 

Product Code                                            19-0780

UN/ID no.             UN 1950 IMCO Class 2.1 None Synonyms 

Recommended use of the chemical and restrictions on use 

Recommended Use                                 Hair Styling Product

Uses advised against                             No information available 

Details of the supplier of the safety data sheet 

Supplier Identification 

Address 

Telephone 

E-mail

Emergency telephone number  

Drybar Products LLC/Helen of     Troy

1 Helen of Troy Plaza

El Paso,Texas, 79912 Phone: 1-800-487-7273 prousso@helenoftroy.com 

VelocityEHS (Chemtel) 1-800-255-3924

2. HAZARDS IDENTIFICATION

Classification 

OSHA Regulatory Status 

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) 

Carcinogenicity 

Category 1A 

Flammable aerosols 

 

Category 1 

 

Gases under pressure 

 

Compressed gas 

 

Label elements  

Emergency Overview 

Danger 

Hazard statements 

May cause cancer        

Extremely flammable aerosol        

Contains gas under pressure; may explode if heated 

 

_____________________________________________________________________________________________ 


Obtain special instructions before use 

Do not handle until all safety precautions have been read and understood 

Use personal protective equipment as required 

Keep away from heat/sparks/open flames/hot surfaces. - No smoking 

Pressurized container: Do not pierce or burn, even after use 

Do not spray on an open flame or other ignition source   

Precautionary Statements - Response 

IF exposed or concerned: Get medical advice/attention 

Precautionary Statements - Storage 

Store locked up 

Protect from sunlight. Store in a well-ventilated place 

Do not expose to temperatures exceeding 122 °F (50 °C) 

Precautionary Statements - Disposal 

Dispose of contents/container to an approved waste disposal plant 

Hazards not otherwise classified (HNOC) Not applicable   

Other Information 

Toxic to aquatic life with long lasting effects Harmful to aquatic life 

Unknown acute toxicity                              99.262% of the mixture consists of ingredient(s) of unknown toxicity 

3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance 

Synonyms                                                  None. 

Chemical Name 

CAS No. 

Weight-% 

 

Ethanol 

64-17-5

15 - 40 

 

Aminomethyl propanol 

124-68-5

0.1 - 1 

 

4. FIRST AID MEASURES

Description of first aid measures 

 

Eye contact     

Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.   

Skin contact 

Discontinue use of product. Wash affected area with soap and water. If discomfort persists, consult a physician.   

Inhalation 

If respiratory irritation occurs, remove individual to fresh air. If discomfort persists, consult a physician. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. If breathing is affected due to intentional inhalation, remove patient to fresh air, get emergency attention, and administer artificial respiration and/or oxygen.   

 

Ingestion  

Clean mouth with water and drink afterwards plenty of water. 

 

Most important symptoms and effects, both acute and delayed 

Symptoms                                                  No information available.   

Indication of any immediate medical attention and special treatment needed Note to physicians     Treat symptomatically.   

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media 

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. 

Unsuitable extinguishing media  ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). CAUTION: Use of water spray when fighting fire may be inefficient. 

Specific hazards arising from the chemical No information available.   

Hazardous combustion products Hydrocarbons, Volatile organic compounds, Halocarbons, Dimethyl Ether 

Explosion data  

Sensitivity to Mechanical Impact No information available. 

        Sensitivity to Static Discharge      May be ignited by heat, sparks or flames. 

Protective equipment and precautions for firefighters 

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.   

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures 

Personal precautions  

Ensure adequate ventilation, especially in confined areas. 

For emergency responders 

Environmental precautions 

Be aware that gases can spread at ground level (heavier than air) and pay attention to the wind direction. Remove all sources of ignition. Pay attention to flashback. Wear respiratory protection. Ventilate the area.   

Environmental precautions 

The product ingredients are expected to be safe for the environment at concentrations predicted under normal use and accidental spill scenarios. Packaging components are compatible with conventional solid waste management practices. Aerosol containers are recyclable when empty.   

Methods and material for containment and cleaning up 

Methods for containment 

Prevent further leakage or spillage if safe to do so.   

Methods for cleaning up  

Dispose of in accordance with federal, state and local regulations. 

7. HANDLING AND STORAGE

Precautions for safe handling 

Advice on safe handling                       Flammable. Avoid heat, sparks, flame, or smoking during use. Use only in well-ventilated areas. Contents under pressure. Do not crush, puncture or incinerate. Keep out of reach of children.   

Conditions for safe storage, including any incompatibilities 

Storage Conditions 

Store as an aerosol under the proper aerosol classification level in accordance with NFPA 30B. Store in a cool, dry, well-ventilated area below 120°F. Warehousing should be in compliance with local, state, and federal codes, as well as the regulations of your insurance carrier.      

Packaging materials  

No information available.   

Incompatible materials 

None known based on information supplied. 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters 

Exposure Guidelines                              This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.   

Chemical Name 

ACGIH TLV 

OSHA PEL 

NIOSH IDLH 

Ethanol 64-17-5

STEL: 1000 ppm 

TWA: 1000 ppm  

TWA: 1900 mg/m3  

(vacated) TWA: 1000 ppm  

(vacated) TWA: 1900 mg/m3 

IDLH: 3300 ppm  

TWA: 1000 ppm  

TWA: 1900 mg/m3 

Appropriate engineering controls 

Engineering Controls                             Showers  

Eyewash stations  

Ventilation systems. 

Individual protection measures, such as personal protective equipment 

        Eye/face protection                           Avoid contact with eyes. 

        Skin and body protection               No special technical protective measures are necessary. 

Respiratory protection                    No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required.   

General Hygiene Considerations         Handle in accordance with good industrial hygiene and safety practice. 

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties 

Physical state 

Aerosol   

 

 

Appearance    

Spray   

Odor    

No information available 

Color  

 

No information available 

Odor threshold 

 

No information available 

Property 

 

Values 

Remarks  • Method 

 

 

pH 

 

No information available 

 

 

Melting point / freezing point 

 

No information available 

 

 

Boiling point / boiling range     

No information available 

 

 

Boiling point concentrate  

78.5  °C   

 

 

 

Boiling point propellant     

25.1     °C   

Flash point     

 

No information available 

Flash point concentrate     

13  °C  55.4     °F   

Flash point propellant     

-50  °C

Evaporation rate     

No information available

Flammability (solid, gas) 

 

Flammability Limit in Air 

No information available

Upper flammability limit: 

No information available 

 Lower flammability limit:  

No information available 

Vapor pressure      

No information available 

Vapor density     

 

No information available 

Relative density     

No information available 

Water solubility     

No information available 

Solubility in other solvents     

No information available 

Partition coefficient  

 

No information available 

Autoignition temperature     

No information available 

Decomposition temperature 

 

No information available 

Kinematic viscosity     

No information available 

Dynamic viscosity     

 

No information available 

Explosive properties  

No information available 

Oxidizing properties  

Other Information 

No information available 

Softening point     

No information available 

Molecular weight 

No information available 

VOC Content (%) 

<55%      

Density  

0.7908 g/cc   

Bulk density     

No information available 

10. STABILITY AND REACTIVITY

Reactivity 

No data available 

 

Chemical stability

Stable under recommended storage conditions. 

Possibility of Hazardous Reactions None under normal processing.   

Conditions to avoid 

Extremes of temperature and direct sunlight. 

Incompatible materials 

None known based on information supplied. 

Hazardous Decomposition Products 

None known based on information supplied. 

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure 

Product Information 

No data available 

 

Inhalation  

No data available. 

 

Eye contact 

No data available. 

 

 

Skin contact 

No data available. 

 

 

Ingestion 

No data available. 

 

 

Chemical Name 

Oral LD50 

Dermal LD50 

Inhalation LC50 

 

Ethanol 64-17-5

= 7060 mg/kg  ( Rat ) 

= 124.7 mg/L  ( Rat ) 4 h 

 

Aminomethyl propanol 124-68-5

= 2900 mg/kg  ( Rat ) 

> 2000 mg/kg  ( Rabbit )








Information on toxicological effects 

Symptoms                                                  No information available.   

Delayed and immediate effects as well as chronic effects from short and long-term exposure 

Sensitization      No information available. Germ cell mutagenicity                No information available. Carcinogenicity   No information available. 

Chemical Name  

 

ACGIH 

IARC 

NTP 

OSHA 

Ethanol 64-17-5

 

A3 

Group 1 

Known 

Reproductive toxicity  

No information available. 

 

 

STOT - single exposure  

No information available. 

 

 

STOT - repeated exposure 

No information available. 

 

 

Aspiration hazard     

No information available. 

 

 

Numerical measures of toxicity     - Product Information 

The following values are calculated based on chapter 3.1 of the GHS document  

       ATEmix (oral)                                    6,317.00 

       ATEmix (dermal)                               12,725.00 

       ATEmix (inhalation-dust/mist)      127.10 

 

12. ECOLOGICAL INFORMATION

 

Ecotoxicity

43.918 % of the mixture consists of components(s) of unknown hazards to the aquatic environment 

Chemical Name 

Algae/aquatic plants 

Fish 

Crustacea 

Ethanol 64-17-5

12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h 

Pimephales promelas mg/L LC50 

static  

9268 - 14221: 48 h Daphnia magna mg/L LC50 10800: 24 h Daphnia 

magna mg/L EC50 2: 48 h Daphnia magna mg/L EC50 Static  

Disiloxane 107-46-0

3.02: 96 h Oncorhynchus mykiss mg/L LC50 flow-through  

314: 24 h Daphnia magna mg/L 

EC50  

Aminomethyl propanol 124-68-5

520: 72 h Desmodesmus subspicatus mg/L EC50  

190: 96 h Lepomis macrochirus mg/L LC50 static  

193: 48 h Daphnia magna mg/L 

EC50  

Glycerin 56-81-5

51 - 57: 96 h Oncorhynchus mykiss mL/L LC50 static  

500: 24 h Daphnia magna mg/L 

EC50  

Persistence and degradability No information available.   

Bioaccumulation

No information available. 

 

Chemical Name 

Partition coefficient 

 

Ethanol 64-17-5

-0.32

Other adverse effects 

No information available 

 






13. DISPOSAL CONSIDERATIONS

Waste treatment methods 

 

 

Disposal of wastes  

Disposal should be in accordance with applicable regional, national and local laws and regulations.   

 

Contaminated packaging 

Do not reuse container. 

 

 

Chemical Name 

California Hazardous Waste Status 

 

Ethanol 64-17-5

 

 

Toxic Ignitable 

 

 

 

 

 

 

14. TRANSPORT INFORMATION

 

 

DOT 

Regulated   

 

 

UN/ID no.  

UN 1950 IMCO Class 2.1   

 

 

Proper shipping name 

Aerosols, Flammable - Limited Quantity 

 

 

Hazard Class  

2.1   

 

 

Packing Group  

n/a   

 

 

IATA 

Regulated   

 

 

UN/ID no.  

UN 1950 IMCO Class 2.1   

 

 

Proper shipping name 

Aerosols, Flammable - Limited Quantity 

 

 

Hazard Class  

2.1   

 

 

Packing Group  

n/a   

 

 

IMDG 

Regulated   

 

 

UN/ID no.  

UN 1950 IMCO Class 2.1   

 

 

Proper shipping name 

Aerosols, Flammable - Limited Quantity 

 

 

Hazard Class  

21   

 

 

Packing Group  

n/a   

 

 

EmS-No.  

Chemtrec 1-800-424-9300   

 

 

 

15. REGULATORY INFORMATION

 








International Inventories 

TSCA                                                           Does not comply 

DSL/NDSL                                                  Does not comply 

EINECS/ELINCS                                        Does not comply 

ENCS                                                           Does not comply 

IECSC                                                          Does not comply 

KECL                                                           Does not comply 

PICCS                                                          Does not comply 

AICS                                                             Does not comply 

Legend: 


 

 TSCA  - United States Toxic Substances Control Act Section 8(b) Inventory   

 DSL/NDSL  - Canadian Domestic Substances List/Non-Domestic Substances List   

 EINECS/ELINCS  - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances  ENCS  - Japan Existing and New Chemical Substances   

 IECSC  - China Inventory of Existing Chemical Substances   

 KECL  - Korean Existing and Evaluated Chemical Substances   

 PICCS  - Philippines Inventory of Chemicals and Chemical Substances   

 AICS  - Australian Inventory of Chemical Substances   

US Federal Regulations 

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA).  This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372   

SARA 311/312 Hazard Categories 

 

Acute health hazard  

No 

Chronic Health Hazard  

No 

Fire hazard  

No 

Sudden release of pressure hazard 

No 

Reactive Hazard  

No 

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)   

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive 

Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355).   There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material   

US State Regulations 

California Proposition 65 

This product does not contain any Proposition 65 chemicals 

U.S. State Right-to-Know Regulations 

U.S. EPA Label Information   

EPA Pesticide Registration Number  Not applicable 

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

NFPA 

 

Health hazards       0            Flammability      

Instability           0   

Physical and Chemical 

 

 

 

Properties     -   

 

HMIS 

 

Health hazards       0            Flammability      

Physical hazards       

Personal protection          

Issue Date     

29-Jan-2018   

 

 

Revision Date     

10/8/22      

 

 

Revision Note       

                         Emergency company data updated. DR

 

No information available   Disclaimer 

The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.   

End of Safety Data Sheet